question archive You are given a 200-mL sample of surface water from Lake Ontario, and asked to determine the chemical oxygen demand (COD) of the sample

You are given a 200-mL sample of surface water from Lake Ontario, and asked to determine the chemical oxygen demand (COD) of the sample

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You are given a 200-mL sample of surface water from Lake Ontario, and asked to determine the chemical oxygen demand (COD) of the sample. To do so, you reflux the sample with 15 mL of a 0.2M K2Cr2O7 standard solution for 2 hours, then titrate the excess dichromate using 20.0 mL of a 0.3M Fe2+ solution. What was the COD of the sample (reported in mol/L of O2)?

 

Reminder: Cr2O72- consumes 6e-, Fe2+ offers 1e-.

 

A) The COD of the sample is 0.010 mol/L O2

B) The COD of the sample is 0.008 mol/L O2

C) The COD of the sample is 0.015 mol/L O2

D) The COD of the sample is 0.005 mol/L O2

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