Using your knowledge of intermolecular forces and gas behaviors please explain why the Van deer Waal's constants for the following gases are trending in the way shown: a

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Using your knowledge of intermolecular forces and gas behaviors please explain why the Van deer Waal's constants for the following gases are trending in the way shown:

a.     Carbon dioxide         

a (L²bar/mol²) - 3.640            b (L/mol) - 0.04267

b.    Carbon disulfide        

a (L²bar/mol²) -11.77             b (L/mol) - 0.07685

c.    Carbon monoxide      

a (L²bar/mol²) - 1.505            b (L/mol) - 0.03985

d.    Carbon tetrachloride  

a (L²bar/mol²) - 19.7483        b (L/mol) - 0.1281