question archive 1) In part A, the crucible was not "fired" before burning the magnesium
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1) In part A, the crucible was not "fired" before burning the magnesium. When the magnesium was burned, volatile impurities in the crucible were burned off. Will this error increase, decrease, or not affect the ratio of magnesium to oxygen determined and the empirical formula found?
2. In part A, a student did not completely burn all the magnesium and some un-burned magnesium remained. How will this affect the empirical formula found?
3. In part A, a student forgot to allow some air (oxygen) to get into the crucible while burning the magnesium. The oxygen insufficiency resulted in the formation of the magnesium nitride (Mg3N2) instead of the magnesium oxide. How will this error affect the magnesium-to-oxygen ratio and the empirical formula found?
4. In part B, a student burned the hydrate over a very intense heat, and some of the copper(II) sulfate was turned into a copper(II) oxide. Will the number of waters of hydration determined be too high, too low, or remain the same?
5. In part B, a student forgot to place the heated sample in the dessicator while cooling, and some water was re-absorbed by the copper (II) chloride. Will the number of waters of hydration determined be too high, too low, or remain the same?
Answer:
1.It will not affect theratio of magnesium to oxygen because,only volatile part has gone .We require only the quantity of magnesium or oxygen for calculating empirical formula.
2.Incomplete burning of magnesium means,the quantity of magnesium reacted will be lesser than taken. So in the calculated,result obtained will show more oxygen than the actual quantity if the quntity of magnesium remaining is not considered.
3.Magnesium consumed will be more than the actual value if properly done.In the empirical formula obtaned, there will be more number of magnesium than actual.
4.The calculated water of hydration will be more than actual since the final weight will be lower than actual.
5.The calculated water of hydration will be lower than actual since The final weight will be higher.