question archive Draw the organic product(s) of the following reaction
Draw the organic product(s) of the following reaction
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Draw the organic product(s) of the following reaction. + + aqueous H,SO. + NaCn aqueous 4,60, L. NacN You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. 1 Aa 8 , . C - ® - // //- ooo - [F ChemDoodle"
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Aldehyde and ketone reacts with nucleophile(CN-)
As the number of alkyl groups around carbonyl group increases the reactivity of carbonyl group decreases.
In the above molecule keto group has greater steric crowding so it cant make stable transition state so nuclephilic addition wont take place.
Aldehyde functional group is most accessible to CN- so it forms 100% product.
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