question archive Bromination reaction of alkenes Consider the following two reactions:  Reaction #1:  Bromination reaction with 1-methylcyclohexene Solvent: Diethyl ether Reagent: Br2 Temperature of the reaction: room temperature The organic layer was extracted by using a separatory funnel and adding H2O Product #1 was obtained from recrystallization after extracting the organic layer Reaction #2: Bromination reaction with 2-butene Solvent: Diethyl ether Reagent: Br2 Temperature of the reaction: room temperature  Product #2 was obtained by extracting the organic layer by using a separatory funnel and adding H2O No recrystallization was needed Why is the product of reaction #2 not a mixture of products as in reaction #1?

Bromination reaction of alkenes Consider the following two reactions:  Reaction #1:  Bromination reaction with 1-methylcyclohexene Solvent: Diethyl ether Reagent: Br2 Temperature of the reaction: room temperature The organic layer was extracted by using a separatory funnel and adding H2O Product #1 was obtained from recrystallization after extracting the organic layer Reaction #2: Bromination reaction with 2-butene Solvent: Diethyl ether Reagent: Br2 Temperature of the reaction: room temperature  Product #2 was obtained by extracting the organic layer by using a separatory funnel and adding H2O No recrystallization was needed Why is the product of reaction #2 not a mixture of products as in reaction #1?

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Bromination reaction of alkenes

Consider the following two reactions: 

Reaction #1: 

  • Bromination reaction with 1-methylcyclohexene
  • Solvent: Diethyl ether
  • Reagent: Br2
  • Temperature of the reaction: room temperature
  • The organic layer was extracted by using a separatory funnel and adding H2O
  • Product #1 was obtained from recrystallization after extracting the organic layer

Reaction #2:

  • Bromination reaction with 2-butene
  • Solvent: Diethyl ether
  • Reagent: Br2
  • Temperature of the reaction: room temperature
  •  Product #2 was obtained by extracting the organic layer by using a separatory funnel and adding H2O
  • No recrystallization was needed

Why is the product of reaction #2 not a mixture of products as in reaction #1?

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