question archive Consider the Gibbs energies at 25 ?C

Consider the Gibbs energies at 25 ?C

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Consider the Gibbs energies at 25 ?C.

SubstanceSubstance ΔG?f (kJ⋅mol−1)ΔGf? (kJ·mol−1)
Ag+(aq)Ag+(aq) 77.177.1
Cl−(aq)Cl−(aq) −131.2−131.2
AgCl(s)AgCl(s) −109.8−109.8
Br−(aq)Br−(aq) −104.0−104.0
AgBr(s)AgBr(s) −96.9−96.9

(a) Calculate ΔG?rxn for the dissolution of AgCl(s)AgCl(s).

kJ⋅mol−1

(b) Calculate the solubility-product constant of AgCl.

K=

(c) Calculate ΔG?rxnΔGrxn? for the dissolution of AgBr(s)AgBr(s).

kJ⋅mol−1kJ⋅mol−1

(d) Calculate the solubility-product constant of AgBr.

K=K=

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